2-(1-Adamantyl)-4-bromoanisole at 123 K
نویسنده
چکیده
IN THE TITLE COMPOUND [SYSTEMATIC NAME: 2-(1-adamantyl)-4-bromo-1--methoxy-benzene], C(17)H(21)BrO, two weak intra-molecular C-H⋯O hydrogen bonds influence the mol-ecular conformation. The crystal packing exhibits C-H⋯π inter-actions, with a relatively short inter-molecular C⋯Cg contact of 3.568 (5) Å, where Cg is the centroid of the benzene ring. The crystal studied exhibited inversion twinning.
منابع مشابه
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متن کاملThermally controlling the singlet–triplet energy gap of a diradical in the solid state† †Electronic supplementary information (ESI) available: Crystallographic data in CIF formats, powder EPR spectra, crystal structures and theoretical calculation. CCDC 1430382 and 1430383. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc01825d Click here for additional data file. Click here for additional data file.
Table S1. Crystal data and structure refinement.......................................... ....................................S2 Figure S1. Powder EPR spectra of 1•2[Al(ORF)4] at various temperatures (120-170K)..............................S3 Figure S2. Powder EPR spectra of 1•2[Al(ORF)4] at various temperatures (190-290K)... ...........................S4 Figure S3. Powder EPR spectrum of 1•2[A...
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A novel Schiff base compound, C(20)H(27)NO(2), was obtained by a condensation of rimantadine and 2-hy-droxy-4-meth-oxy-benzaldehyde. An intra-molecular O-H⋯N hydrogen bond supports the phenol-imine tautomeric form. The adamantane and imino-methyl-4-meth-oxy-phenol units are arranged in a folded conformation [C-N-C-C torsion angle = 110.9 (3)°]. In the crystal, highly hydro-phobic adamantane moi...
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008